Reversible structural transformation induced switchable single-molecule magnet behavior in lanthanide metal-organic frameworks

Mengmeng Wang; Xixi Meng; Fen Song; Yanfei He; Wei Shi; Hongling Gao; Jinkui Tang; Cheng Peng

doi:10.1039/c8cc06058d

Reversible structural transformation induced switchable single-molecule magnet behavior in lanthanide metal-organic frameworks

Chem Commun (Camb). 2018 Sep 6;54(72):10183-10186. doi: 10.1039/c8cc06058d.

Authors

Mengmeng Wang¹, Xixi Meng, Fen Song, Yanfei He, Wei Shi, Hongling Gao, Jinkui Tang, Cheng Peng

Affiliation

¹ Department of Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China. shiwei@nankai.edu.cn pcheng@nankai.edu.cn.

PMID: 30137097
DOI: 10.1039/c8cc06058d

Abstract

Switchable "on/off" single-molecule magnet (SMM) behavior can be realized in lanthanide metal-organic frameworks (Ln-MOFs) tuned by the temperature-induced change of the coordination geometry of the lanthanide centers.