Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Xin-Xiong Li; Lin-Jie Zhang; Cai-Yan Cui; Rui-Hu Wang; Guo-Yu Yang

doi:10.1021/acs.inorgchem.8b01528

Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Inorg Chem. 2018 Aug 20;57(16):10323-10330. doi: 10.1021/acs.inorgchem.8b01528. Epub 2018 Aug 10.

Authors

Xin-Xiong Li^{1

2}, Lin-Jie Zhang², Cai-Yan Cui², Rui-Hu Wang², Guo-Yu Yang³

Affiliations

¹ State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry , Fuzhou University , Fuzhou , Fujian 350108 , China.
² State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter , Chinese Academy of Sciences , Fuzhou , Fujian 350002 , China.
³ MOE Key Laboratory of Cluster Science, School of Chemistry , Beijing Institute of Technology , Beijing 100081 , China.

PMID: 30094991
DOI: 10.1021/acs.inorgchem.8b01528

Abstract

Two unprecedented examples of cluster organic frameworks (TBA)₃Cu[V₆O₁₃(L)₂]₂·4DEF (2) (TBA)Ag[V₆O₁₃(L)₂] solvent (3) (TBA = tetrabutylammonium, H₃L = tris(hydroxymethyl)-4-picoline, DEF = N, N'-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.