Photocatalytic decomposition effect of erbium doped cerium oxide nanostructures driven by visible light irradiation: Investigation of cytotoxicity, antibacterial growth inhibition using catalyst

J Photochem Photobiol B. 2018 Aug:185:275-282. doi: 10.1016/j.jphotobiol.2018.06.011. Epub 2018 Jun 21.

Abstract

Cerium (IV) oxide (CeO2) is the most accessible noble rare earth metal oxide for the excitation of the excitons by light-harvesting performance. The present work is focused on Erbium doped ceria nanoparticles that were beneficially obtained by hydrothermal method from cerium nitrate and Erbium nitrate as precursors for decomposition of Rhodamine-B (RhB) dye in the polluted waste water removed from the industries. Dye removal efficiency of the catalyst was found to be nearly ~94%. The structural phases, functional groups and the transitions are identified with the help of various techniques. XRD pattern determines the development of cubic phase with the particle size is 20 nm. Highly crystalline nature of as-synthesized nanomaterials with an average diameter of 35 nm was investigated by HRSEM. The crystalline size, shape and textural morphology, of the Erbium doped ceria nanostructures were analysed by HRTEM. Our results suggest, that the concentration of OH- ion determines the lattice constants and oxygen vacancy in the nanostructures which stimulate the probability of photocatalytic decomposition effect of organic pollutants, due to synergistic approach. In this context, both unhydrolyzed things and their swiftly drip from deceased or scratched cells with conceded membranes, even when the cells embrace some are outstanding attention. Although, the loss of viable cells also depends on epithelial cell dynamically conceal of numerous molar matrix.

Keywords: CeO(2); Cytotoxicity; Electron microscopy; Photocatalytic studies; Rhodamine -B.

MeSH terms

  • A549 Cells
  • Anti-Bacterial Agents / chemistry*
  • Anti-Bacterial Agents / pharmacology
  • Catalysis
  • Cell Membrane / drug effects
  • Cell Membrane / radiation effects
  • Cerium / chemistry*
  • Erbium / chemistry*
  • Gram-Negative Bacteria / drug effects
  • Gram-Negative Bacteria / radiation effects
  • Gram-Positive Bacteria / drug effects
  • Gram-Positive Bacteria / radiation effects
  • Humans
  • Light*
  • Microscopy, Electron, Scanning
  • Microscopy, Electron, Transmission
  • Nanostructures / chemistry*
  • Nanostructures / toxicity
  • Particle Size
  • Rhodamines / chemistry
  • Spectroscopy, Fourier Transform Infrared
  • X-Ray Diffraction

Substances

  • Anti-Bacterial Agents
  • Rhodamines
  • Cerium
  • ceric oxide
  • Erbium
  • rhodamine B