Synthesis and Electrochemical Performance of Molybdenum Disulfide-Reduced Graphene Oxide-Polyaniline Ternary Composites for Supercapacitors

Front Chem. 2018 Jun 12:6:218. doi: 10.3389/fchem.2018.00218. eCollection 2018.

Abstract

Molybdenum disulfide/reduced graphene oxide/polyaniline ternary composites (MoS2/rGO/PANI) were designed and synthesized by a facile two-step approach including hydrothermal and in situ polymerization process. The MoS2/rGO/PANI composites presented an interconnected 3D network architecture, in which PANI uniformly coated the outer surface of the MoS2/rGO binary composite. The MoS2/rGO/PANI composites with a weight percent of 80% (MGP-80) exhibits the best specific capacitance (570 F g-1 at 1 A g-1) and cycling stabilities (78.6% retained capacitance after 500 cycles at 1 A g-1). The excellent electrochemical capacitive performance is attributed to its 3D network structure and the synergistic effects among the three components that make the composites obtain both pseudocapacitance and double-layer capacitance.

Keywords: molybdenum disulfide; polyaniline; reduced graphene oxide; supercapacitors; ternary composites.