Rare earth arylsilazido compounds with inequivalent secondary interactions

Chem Commun (Camb). 2018 Jun 28;54(53):7318-7321. doi: 10.1039/c8cc03186j.

Abstract

A new bulky silazido ligand, -N(SiHMe2)Dipp (Dipp = C6H3-2,6-iPr2), supports planar, three-coordinate homoleptic rare earth complexes Ln{N(SiHMe2)Dipp}3 (Ln = Sc, Y, and Lu), each containing three secondary Ln↼HSi interactions and one agostic CH bond. Y{N(SiHMe2)Dipp}3 and acetophenone react via hydrosilylation, rather than by insertion into the Y-N bond or by enolate formation.