Nanoscale Zero-Valent Iron Decorated on Bentonite/Graphene Oxide for Removal of Copper Ions from Aqueous Solution

Jicheng Shao; Xiaoniu Yu; Min Zhou; Xiaoqing Cai; Chuang Yu

doi:10.3390/ma11060945

Nanoscale Zero-Valent Iron Decorated on Bentonite/Graphene Oxide for Removal of Copper Ions from Aqueous Solution

Materials (Basel). 2018 Jun 4;11(6):945. doi: 10.3390/ma11060945.

Authors

Jicheng Shao¹, Xiaoniu Yu², Min Zhou³, Xiaoqing Cai⁴, Chuang Yu⁵

Affiliations

¹ College of Civil Engineering and Architecture, Wenzhou University, Wenzhou 325035, China. shaojicheng@aliyun.com.
² College of Civil Engineering and Architecture, Wenzhou University, Wenzhou 325035, China. xnyu@wzu.edu.cn.
³ College of Civil Engineering and Architecture, Wenzhou University, Wenzhou 325035, China. zhoumin480855165@aliyun.com.
⁴ College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China. cxq@wzu.edu.cn.
⁵ College of Civil Engineering and Architecture, Wenzhou University, Wenzhou 325035, China. geoyuchuang@163.com.

Abstract

The removal efficiency of Cu(II) in aqueous solution by bentonite, graphene oxide (GO), and nanoscale iron decorated on bentonite (B-nZVI) and nanoscale iron decorated on bentonite/graphene oxide (GO-B-nZVI) was investigated. The results indicated that GO-B-nZVI had the best removal efficiency in different experimental environments (with time, pH, concentration of copper ions, and temperature). For 16 hours, the removal efficiency of copper ions was 82% in GO-B-nZVI, however, it was 71% in B-nZVI, 26% in bentonite, and 18% in GO. Bentonite, GO, B-nZVI, and GO-B-nZVI showed an increased removal efficiency of copper ions with the increase of pH under a certain pH range. The removal efficiency of copper ions by GO-B-nZVI first increased and then fluctuated slightly with the increase of temperature, while B-nZVI and bentonite increased and GO decreased slightly with the increase of temperature. Lorentz-Transmission Electron Microscope (TEM) images showed the nZVI particles of GO-B-nZVI dispersed evenly with diameters ranging from 10 to 86.93 nm. Scanning electron microscope (SEM) images indicated that the nanoscale iron particles were dispersed evenly on bentonite and GO with no obvious agglomeration. The q_e,cal (73.37 mg·g^-1 and 83.89 mg·g^-1) was closer to the experimental value q_e,exp according to the pseudo-second-order kinetic model. The q_m of B-nZVI and GO-B-nZVI were 130.7 mg·g^-1 and 184.5 mg·g^-1 according to the Langmuir model.

Keywords: adsorption; bentonite; copper ions; graphene oxide; zero-valent iron.