Dual-Gated Transistor Platform for On-Site Detection of Lead Ions at Trace Levels

Anal Chem. 2018 Jun 19;90(12):7399-7405. doi: 10.1021/acs.analchem.8b00841. Epub 2018 May 29.

Abstract

On-site monitoring of heavy metals in drinking water has become crucial because of several high profile instances of contamination. Presently, reliable techniques for trace level heavy metal detection are mostly laboratory based, while the detection limits of contemporary field-based methods are barely meeting the exposure limits set by regulatory bodies such as the World Health Organization (WHO). Here, we show an on-site deployable, Pb2+ sensor on a dual-gated transistor platform whose lower detection limit is 2 orders of magnitude better than the traditional sensor and 1 order of magnitude lower than the exposure limit set by WHO. The enhanced sensitivity of our design is verified by numerically solving PNP (Planck-Nernst-Poisson) model. We demonstrate that the enhanced sensitivity is due to the suppression of ionic flux. The simplicity and the robustness of the design make it applicable for on-site screening, thereby facilitating rapid response to contamination events.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Drinking Water / chemistry*
  • Ions
  • Lead / analysis*
  • Limit of Detection
  • Metals, Heavy / analysis
  • Water Pollutants, Chemical / analysis

Substances

  • Drinking Water
  • Ions
  • Metals, Heavy
  • Water Pollutants, Chemical
  • Lead