Manganese-Catalyzed Hydrosilylation Reactions

Xiaoxu Yang; Congyang Wang

doi:10.1002/asia.201800618

Manganese-Catalyzed Hydrosilylation Reactions

Chem Asian J. 2018 Sep 4;13(17):2307-2315. doi: 10.1002/asia.201800618. Epub 2018 Jul 16.

Authors

Xiaoxu Yang^{1

2}, Congyang Wang^{1

2}

Affiliations

¹ Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
² University of Chinese Academy of Sciences, Beijing, 100049, China.

PMID: 29781172
DOI: 10.1002/asia.201800618

Abstract

Over the past few decades, manganese-catalyzed hydrosilylation of C=O or C=C/C≡C unsaturated bonds have undergone enormous developments. In this focus review, the hydrosilylation reactions of alkenes, alkynes, and carbonyl-containing substrates catalyzed by manganese complexes are summarized. Moreover, the mechanisms of the manganese-catalyzed hydrosilylation are briefly discussed.

Keywords: alkenes; alkynes; carbonyl bonds; hydrosilylation; manganese.

Publication types

Review

Grants and funding

21472194, 21772202, 21521002/National Natural Science Foundation of China