Weak capture in muonic hydrogen (μH) as a probe of the chiral properties and nucleon structure predictions of quantum chromodynamics (QCD) is reviewed. A recent determination of the axial-vector charge radius squared, [Formula: see text], from a model independent z expansion analysis of neutrino-nucleon scattering data is employed in conjunction with the MuCap measurement of the singlet muonic hydrogen capture rate, [Formula: see text], to update the induced pseudoscalar nucleon coupling [Formula: see text] derived from experiment, and [Formula: see text] predicted by chiral perturbation theory. Accounting for correlated errors this implies [Formula: see text], confirming theory at the 8% level. If instead, the predicted expression for [Formula: see text] is employed as input, then the capture rate alone determines [Formula: see text], or together with the independent z expansion neutrino scattering result, a weighted average [Formula: see text]. Sources of theoretical uncertainty are critically examined and potential experimental improvements are described that can reduce the capture rate error by about a factor of 3. Muonic hydrogen can thus provide a precise and independent [Formula: see text] value which may be compared with other determinations, such as ongoing lattice gauge theory calculations. The importance of an improved [Formula: see text] determination for phenomenology is illustrated by considering the impact on critical neutrino-nucleus cross sections at neutrino oscillation experiments.