Stilbenoid Dendrimers

Angew Chem Int Ed Engl. 1998 Mar 16;37(5):643-645. doi: 10.1002/(SICI)1521-3773(19980316)37:5<643::AID-ANIE643>3.0.CO;2-4.

Abstract

A convergent synthesis in which all trans double bonds were constructed by Wittig-Horner reactions produces dendrimers of the general structure 1. With long-chain alkoxy residues on the periphery of the benzene rings, the first two generations display liquid crystalline behavior.

Keywords: Aggregations; Dendrimers; Liquid crystals; Stilbenes; Supramolecular chemistry.