A convergent synthesis in which all trans double bonds were constructed by Wittig-Horner reactions produces dendrimers of the general structure 1. With long-chain alkoxy residues on the periphery of the benzene rings, the first two generations display liquid crystalline behavior.
Keywords: Aggregations; Dendrimers; Liquid crystals; Stilbenes; Supramolecular chemistry.
© 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.