Platinum nanoparticles encapsulated into zeolite Y (Pt@Y catalyst) exhibit excellent catalytic selectivity in the hydrogenation of substituted nitroarenes to form the corresponding aromatic amines, even after complete conversion. With the hydrogenation of p-chloronitrobenzene as a model, the role of zeolite encapsulation toward perfect selectivity can be attributed to constraint of the substrate adsorbed on the platinum surface in an end-on conformation. This conformation results in the activation of only one adsorbed group, with little influence on the other one in the molecule. Owing to a much lower apparent activation energy of Pt@Y for the hydrogenation of a separately adsorbed nitro group than that of the adsorbed chloro group, the Pt@Y catalyst can prevent hydrodechlorination of p-chloronitrobenzene under mild conditions. Moreover, such a conformation results in a reduced adsorption energy of target p-chloroaniline on the platinum surface; thus suppressing the reactivity of hydrodechlorination of p-chloroaniline to circumvent further C-Cl bond breakage.
Keywords: hydrogenation; nanoparticles; platinum; supported catalysts; zeolites.
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