New Ni4Na2-phenylgermsesquioxane architecture: synthesis, structure and slow dynamic behaviour

Alena N Kulakova; Alexey N Bilyachenko; Alexander A Korlyukov; Jérôme Long; Mikhail M Levitsky; Elena S Shubina; Yannick Guari; Joulia Larionova

doi:10.1039/c8dt00900g

New Ni₄Na₂-phenylgermsesquioxane architecture: synthesis, structure and slow dynamic behaviour

Dalton Trans. 2018 May 22;47(20):6893-6897. doi: 10.1039/c8dt00900g.

Authors

Alena N Kulakova¹, Alexey N Bilyachenko, Alexander A Korlyukov, Jérôme Long, Mikhail M Levitsky, Elena S Shubina, Yannick Guari, Joulia Larionova

Affiliation

¹ A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilov str., 28, 119991 Moscow, Russia. bilyachenko@ineos.ac.ru.

PMID: 29708247
DOI: 10.1039/c8dt00900g

Abstract

The first Ni(ii)-based metallagermaniumsesquioxane cage compound [(PhGeO1.5)10(NiO)4(NaO0.5)2] presents a sandwich-like structure where two germsesquioxane cages are linked through an {NiO}4 core and exhibits slow dynamics of the magnetization.