An advanced pretreatment strategy involving hydrodynamic and acoustic cavitation along with alum coagulation for the mineralization and biodegradability enhancement of tannery waste effluent

Shivendu Saxena; Sunil Rajoriya; Virendra Kumar Saharan; Suja George

doi:10.1016/j.ultsonch.2018.02.035

An advanced pretreatment strategy involving hydrodynamic and acoustic cavitation along with alum coagulation for the mineralization and biodegradability enhancement of tannery waste effluent

Ultrason Sonochem. 2018 Jun:44:299-309. doi: 10.1016/j.ultsonch.2018.02.035. Epub 2018 Feb 22.

Authors

Shivendu Saxena¹, Sunil Rajoriya¹, Virendra Kumar Saharan², Suja George³

Affiliations

¹ Department of Chemical Engineering, MNIT, Jaipur 302017, India.
² Department of Chemical Engineering, MNIT, Jaipur 302017, India. Electronic address: vksaharan.chem@mnit.ac.in.
³ Department of Chemical Engineering, MNIT, Jaipur 302017, India. Electronic address: sgeorge.chem@mnit.ac.in.

PMID: 29680615
DOI: 10.1016/j.ultsonch.2018.02.035

Abstract

In the present study, coagulation followed by cavitation was studied as a pretreatment tool for tannery waste effluent (TWE) with the aim of reducing its COD, TOC, TSS etc. and enhancing its biodegradability to make it suitable for anaerobic digestion. Initially, coagulation was applied to TWE using alum as a coagulant. The residual pH of treated effluent was found to be around pH of 4.5 where maximum COD and TSS reduction was achieved. In order to enhance the efficiency of pretreatment process, coagulated tannery waste effluent (CTWE) was further subjected to hydrodynamic cavitation (HC) and ultrasonication (US). In case of HC, effect of process parameters such as inlet pressure and dilution on the treatment of CTWE was initially investigated. Lower operating pressure (5 bar) was more favorable for the treatment of CTWE using HC in order to enhance the biodegradability index (BI) from 0.14 to 0.57 in 120 min. The CTWE samples when subjected to 50% dilution, HC pretreatment exhibited higher percentage and quantum reduction in TOC and COD. On the other hand, pretreatment of TWE using coagulation followed by US demonstrated that BI of effluent was enhanced from 0.10 to 0.41 in 150 min. Energy efficiency evaluation for all processes at their optimized conditions was done based on the actual amount of COD reduced per unit energy delivered to the system. Coagulation followed by HC for the pretreatment of TWE was found to be six times more energy efficient as compared to coagulation followed by US.

Keywords: Biodegradability index; Coagulation; Hydrodynamic cavitation; Tannery waste effluent; Ultrasonication.