Carboxymethyl fenugreek gum: Rheological characterization and as a novel binder for silicon anode of lithium-ion batteries

Abstract

The rheology of carboxymethyl fenugreek gum (CFG) is characterized and applied it as a binder for the silicon anode of lithium-ion batteries (LIBs). First, a series of carboxymethyl fenugreek gum (namely CFG-1, CFG-2 and CFG-3) was prepared and characterized by Fourier transform infrared spectrophotometer and hydrogen nuclear magnetic resonance spectrometry studies. In rheological measurements, the CFG solutions show higher flowability, weaker viscoelastic behavior and better thixotropy than that of fenugreek gum (FG) solution. Furthermore, the higher degrees of substitution (DS) of CFG solutions lead to lower apparent viscosity and higher flow index, weaker elastic effect and smaller relaxation time, and higher viscosity recoverability than those obtained for lower DS of CFG solutions. In electrochemical measurements, the polar hydroxyl and carboxyl groups in the CFG skeleton chain provide bonding points between the CFG binders and the silicon electrode to produce binder-silicon bonds, which cause strong hydrogen bonding, and resulted in excellent electrochemical stability and specific capacity. The electrochemical performances were measured via the silicon electrodes with FG and CFG at 5 wt% content. As the DS is increased, the initial Coulombic efficiency can increase from 88.74% to 91.3%. When the electrode undergoes a volume change, the CFG binder with silicon electrodes can hold high capacity of above 1500 mAh/g after 200 charge-discharge cycles. Therefore, the carboxymethyl fenugreek gum as a binder may also be a novel extended binder-design, with applications for silicon anodes of LIBs.

Keywords: Binder; Carboxymethyl fenugreek gum; Cycling performance; Rheology.