Photocatalytic degradation of aqueous Methyl Orange using nitrogen-doped TiO2 photocatalyst prepared by novel method of ultraviolet-assisted thermal synthesis

Abstract

A nitrogen-doped titanium dioxide composite photocatalyst (N-TiO₂) with heterojunction structures is synthesized by three different approaches: a novel UV-assisted thermal synthesis, annealing, and microwave technique. Photocatalytic activities of synthesized photocatalysts are evaluated by the degradation of Methyl Orange under ultraviolet light types A (UV-A), B (UV-B), and C (UV-C), visible light, and direct sunlight irradiation. Results show that by using N-TiO₂ photocatalyst prepared by the UV-assisted thermal synthesis and annealing, the degradation increases by 16.5% and 20.4%, respectively, compared to that by bare TiO₂. The best results are obtained at a nitrogen to TiO₂ mass ratio of 0.15 (N:TiO₂). The enhancement of the photocatalytic activity observed in the visible range is mainly attributed to the increasing separation rate of photogenerated charge carriers. The novel UV-assisted thermal synthesis has produced encouraging results as a preparation method for the nitrogen-doped TiO₂ photocatalyst; thus, further studies are recommended for process optimization, immobilization, and scale-up to evaluate its applicability in wastewater treatment.

Keywords: Advanced oxidation processes; N–TiO(2); Photocatalysis; Ultraviolet-assisted thermal synthesis.