EDDS as complexing agent for enhancing solar advanced oxidation processes in natural water: Effect of iron species and different oxidants

Abstract

The main purpose of this pilot plant study was to compare degradation of five microcontaminants (MCs) (antipyrine, carbamazepine, caffeine, ciprofloxacin and sulfamethoxazole at 100 μg/L) by solar photo-Fenton mediated by EDDS and solar/Fe:EDDS/S₂O₈^2-. The effects of the Fe:EDDS ratio (1:1 and 1:2), initial iron species (Fe(II) or Fe(III) at 0.1 mM) and oxidizing agent (S₂O₈^2- or H₂O₂ at 0.25-1.5 mM) were evaluated. The higher the S₂O₈^2- concentration, the faster MC degradation was, with S₂O₈^2- consumption always below 0.6 mM and similar degradation rates with Fe(II) and Fe(III). Under the best conditions (Fe 0.1 mM, Fe:EDDS 1:1, S₂O₈^2- 1 mM) antipyrine, carbamazepine, caffeine, ciprofloxacin and sulfamethoxazole at 100 μg/L where 90% eliminated applying a solar energy of 2 kJ/L (13 min at 30 W/m² solar radiation <400 nm). Therefore, S₂O₈^2- promotes lower consumption of EDDS as Fe:EDDS 1:1 was better than Fe:EDDS 1:2. In photo-Fenton-like processes at circumneutral pH, EDDS with S₂O₈^2- is an alternative to H₂O₂ as an oxidizing agent.

Keywords: EDDS; Microcontaminants; Neutral pH; Persulfate; Solar advanced oxidation processes.