Reutilization of the expired tetracycline for lithium ion battery anode

Sci Total Environ. 2018 Jul 15:630:495-501. doi: 10.1016/j.scitotenv.2018.02.126. Epub 2018 Feb 24.

Abstract

Waste antibiotics into the natural environment are the large challenges to the environmental protection and the human health, and the unreasonable disposal of the expired antibiotics is a major pollution source. Herein, to achieve the innocent treatment and the resource recovery, the expired tetracycline was tried to be reutilized as the electrode active material in lithium ion battery (LIB) for the first time. The micro-structure and element component of the expired tetracycline were characterized by scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). Furthermore, the corresponding electrochemical performances were also investigated by galvanostatic charge/discharge and cyclic voltammetry (CV). To be satisfactory, the expired-tetracycline-based electrode delivered the initial specific discharge capacity of 371.6mAh/g and the reversible specific capacity of 304.1mAh/g after 200cycles. The decent results will not only offer an effective strategy to recycle the expired tetracycline, but also shed a new light on the cyclic economy and the sustainable development.

Keywords: Anode; Cyclic utilization; Expired tetracycline; Lithium ion battery; Resource recovery.

MeSH terms

  • Electric Power Supplies*
  • Electrodes
  • Ions
  • Lithium / chemistry*
  • Oxides / chemistry
  • Photoelectron Spectroscopy
  • Recycling*
  • Tetracycline / chemistry*
  • X-Ray Diffraction

Substances

  • Ions
  • Oxides
  • Lithium
  • Tetracycline