Solid-Phase Extraction Coupled to a Paper-Based Technique for Trace Copper Detection in Drinking Water

Environ Sci Technol. 2018 Mar 20;52(6):3567-3573. doi: 10.1021/acs.est.7b05436. Epub 2018 Mar 8.

Abstract

Metal contamination of natural and drinking water systems poses hazards to public and environmental health. Quantifying metal concentrations in water typically requires sample collection in the field followed by expensive laboratory analysis that can take days to weeks to obtain results. The objective of this work was to develop a low-cost, field-deployable method to quantify trace levels of copper in drinking water by coupling solid-phase extraction/preconcentration with a microfluidic paper-based analytical device. This method has the advantages of being hand-powered (instrument-free) and using a simple "read by eye" quantification motif (based on color distance). Tap water samples collected across Fort Collins, CO, were tested with this method and validated against ICP-MS. We demonstrate the ability to quantify the copper content of tap water within 30% of a reference technique at levels ranging from 20 to 500 000 ppb. The application of this technology, which should be sufficient as a rapid screening tool, can lead to faster, more cost-effective detection of soluble metals in water systems.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Copper
  • Drinking Water*
  • Fresh Water
  • Solid Phase Extraction
  • Water Pollutants, Chemical*

Substances

  • Drinking Water
  • Water Pollutants, Chemical
  • Copper