We proffer NH4OH-oriented and pH-dependent growth of ZnO nanostructures via a microwaveassisted growth method. The fabrication of ZnO nanorods (ZNRs), nanoflowers (ZNFs), nanostars (ZNSs), and nanotetrapods (ZNTs) is presented. NH4OH was used as a mineralizer to change the solution pH for nanostructure growth, where temperature and other variables were fixed. Because of an efficient heat transfer and facile growth of nanostructures, a domestic microwave oven was used to facilitate the nanostructure growth in the span of just 10-15 min. The results showed that the growth of ZnO nanostructures was dependent upon the number of growth units and ZnO nuclei present in the solution, which ultimately depend upon the pH of the solution. At the outset, without the addition of NH4OH, the pH of the solution was ~6.8 and the ZNRs were formed in the solution or on a seeded substrate which persisted in the pH range of ~6.8-9. An abrupt change in the shapes and the types of the nanostructures was observed when the pH was boosted beyond 10. A transition from ZNRs to ZNFs was observed at pH 10 and ZNFs were formed at pH 11. The solution gave birth to ZNSs and ZNTs when the pH was further raised to 12 and 13, respectively.