Strong coupling in a microcavity containing β-carotene

Opt Express. 2018 Feb 5;26(3):3320-3327. doi: 10.1364/OE.26.003320.

Abstract

We have fabricated an open-cavity microcavity structure containing a thin film of the biologically-derived molecule β-carotene. We show that the β-carotene absorption can be described in terms of a series of Lorentzian functions that approximate the 0-0, 0-1, 0-2, 0-3 and 0-4 electronic and vibronic transitions. On placing this molecular material into a microcavity, we obtain anti-crossing between the cavity mode and the 0-1 vibronic transition, however other electronic and vibronic transitions remain in the intermediate or weak-coupling regime due to their lower oscillator strength and broader linewidth. We discuss the consequences of strong-coupling for the possible modification of photosynthetic processes, or a re-ordering of allowed and optically-forbidden states.

MeSH terms

  • Energy Transfer*
  • Fluorescent Dyes*
  • Photons
  • Photosynthesis*
  • Semiconductors*
  • Temperature
  • beta Carotene*

Substances

  • Fluorescent Dyes
  • beta Carotene