The electronic transport properties of the delafossite oxides [Formula: see text] are usually understood in terms of two well-separated entities, namely the triangular [Formula: see text] and ([Formula: see text] layers. Here, we review several cases among this extensive family of materials where the transport depends on the interlayer coupling and displays unconventional properties. We review the doped thermoelectrics based on [Formula: see text] and [Formula: see text], which show a high-temperature recovery of Fermi-liquid transport exponents, as well as the highly anisotropic metals [Formula: see text], [Formula: see text], and [Formula: see text], where the sheer simplicity of the Fermi surface leads to unconventional transport. We present some of the theoretical tools that have been used to investigate these transport properties and review what can and cannot be learned from the extensive set of electronic structure calculations that have been performed.
Keywords: 105 Low-Dimension (1D/2D) materials; 106 Metallic materials; 203 Magnetics / Spintronics / Superconductors; 206 Energy conversion / transport / storage / recovery; 401 1st principle calculations; 50 Energy Materials; Delafossites; Nernst effect; anisotropic materials; electronic structure; magnetism; resistivity; thermopower.