An isolable β-diketiminato chlorosilylene

Yun Xiong; Shenglai Yao; Arseni Kostenko; Matthias Driess

doi:10.1039/c8dt00121a

An isolable β-diketiminato chlorosilylene

Dalton Trans. 2018 Feb 13;47(7):2152-2155. doi: 10.1039/c8dt00121a.

Authors

Yun Xiong¹, Shenglai Yao, Arseni Kostenko, Matthias Driess

Affiliation

¹ Technische Universität Berlin, Department of Chemistry: Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany. matthias.driess@tu-berlin.de.

PMID: 29376178
DOI: 10.1039/c8dt00121a

Abstract

The first β-diketiminate ligated chlorosilylene has been synthesised and isolated from the corresponding β-diketiminato dichlorohydrosilane through dehydrochlorination with an N-heterocyclic carbene.