Floc behavior and removal mechanisms of cross-linked Durio zibethinus seed starch as a natural flocculant for landfill leachate coagulation-flocculation treatment

Abstract

This study investigated the behavior and mechanisms of cross-linked Durio zibethinus seed starch (CDSS) flocculants for landfill leachate treatment. A physical-chemical treatment method of coagulation-flocculation process and starch modification were implemented in treating stabilized leachate from Matang Landfill, Perak, Malaysia. In practical, the removal performance of color, COD, suspended solid and turbidity for CDSS flocculants were evaluated by combining with primary coagulant of polyaluminium chloride (PAC). In this study, the application of crosslinking modification for Durio zibethinus seed waste starch flocculants showed good improvement. The impurities removal for colour, COD, suspended solid and turbidity were increased by the addition of CDSS flocculants. Furthermore, the average size of the floc was also increased from 60.24 µm to 89.5 µm. Despite, the addition of CDSS flocculants produced a reduction of PAC coagulant from 2700 mg/L to 2200 mg/L, with 500 mg/L reduction on the PAC dosage dependency. Therefore, these results affirmed the potentials of crosslinked modification for Durio zibethinus seed waste starch flocculants in landfill leachate treatment.

Keywords: Crosslinking modification and leachate treatment; Durio zibethenus; Natural flocculants.