Task-specific design of a hierarchical porous aromatic framework as an ultrastable platform for large-sized catalytic active site binding

Jin-Shi Sun; Li-Ping Jing; Yuyang Tian; Fuxing Sun; Peng Chen; Guangshan Zhu

doi:10.1039/c7cc09767k

Task-specific design of a hierarchical porous aromatic framework as an ultrastable platform for large-sized catalytic active site binding

Chem Commun (Camb). 2018 Feb 8;54(13):1603-1606. doi: 10.1039/c7cc09767k.

Authors

Jin-Shi Sun¹, Li-Ping Jing, Yuyang Tian, Fuxing Sun, Peng Chen, Guangshan Zhu

Affiliation

¹ State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China. pengchen@jlu.edu.cn.

PMID: 29368767
DOI: 10.1039/c7cc09767k

Abstract

An amine-tagged hierarchical porous aromatic framework PAF70-NH2 with ultra-stability and narrowly distributed mesopores was synthesized. PAF70-NH2 has high potential for covalently immobilizing a relatively large-sized catalyst inside its pores. This work gave a perfect example of using PAF70-NH2 as a platform for completely recyclable heterogeneous organocatalysis.