A complete analytical solution of the Fokker-Planck and balance equations for nucleation and growth of crystals

Philos Trans A Math Phys Eng Sci. 2018 Feb 28;376(2113):20170327. doi: 10.1098/rsta.2017.0327.

Abstract

This article is concerned with a new analytical description of nucleation and growth of crystals in a metastable mushy layer (supercooled liquid or supersaturated solution) at the intermediate stage of phase transition. The model under consideration consisting of the non-stationary integro-differential system of governing equations for the distribution function and metastability level is analytically solved by means of the saddle-point technique for the Laplace-type integral in the case of arbitrary nucleation kinetics and time-dependent heat or mass sources in the balance equation. We demonstrate that the time-dependent distribution function approaches the stationary profile in course of time.This article is part of the theme issue 'From atomistic interfaces to dendritic patterns'.

Keywords: mushy layer; nucleation; phase transitions.