Enhanced oxidation of naphthalene using plasma activation of TiO2/diatomite catalyst

Zuliang Wu; Zhoubin Zhu; Xiaodong Hao; Weili Zhou; Jingyi Han; Xiujuan Tang; Shuiliang Yao; Xuming Zhang

doi:10.1016/j.jhazmat.2017.12.052

Enhanced oxidation of naphthalene using plasma activation of TiO₂/diatomite catalyst

J Hazard Mater. 2018 Apr 5:347:48-57. doi: 10.1016/j.jhazmat.2017.12.052. Epub 2017 Dec 25.

Authors

Zuliang Wu¹, Zhoubin Zhu¹, Xiaodong Hao¹, Weili Zhou¹, Jingyi Han¹, Xiujuan Tang¹, Shuiliang Yao¹, Xuming Zhang²

Affiliations

¹ School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou, Zhejiang 310018, China.
² School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou, Zhejiang 310018, China. Electronic address: Zhang.xm@zjsu.edu.cn.

PMID: 29289765
DOI: 10.1016/j.jhazmat.2017.12.052

Abstract

Non-thermal plasma technology has great potential in reducing polycyclic aromatic hydrocarbons (PAHs) emission. But in plasma-alone process, various undesired by-products are produced, which causes secondary pollutions. Here, a dielectric barrier discharge (DBD) reactor has been developed for the oxidation of naphthalene over a TiO₂/diatomite catalyst at low temperature. In comparison to plasma-alone process, the combination of plasma and TiO₂/diatomite catalyst significantly enhanced naphthalene conversion (up to 40%) and CO_x selectivity (up to 92%), and substantially reduced the formation of aerosol (up to 90%) and secondary volatile organic compounds (up to near 100%). The mechanistic study suggested that the presence of the TiO₂/diatomite catalyst intensified the electron energy in the DBD. Meantime, the energized electrons generated in the discharge activated TiO₂, while the presence of ozone enhanced the activity of the TiO₂/diatomite catalyst. This plasma-catalyst interaction led to the synergetic effect resulting from the combination of plasma and TiO₂/diatomite catalyst, consequently enhanced the oxidation of naphthalene. Importantly, we have demonstrated the effectiveness of plasma to activate the photocatalyst for the deep oxidation of PAH without external heating, which is potentially valuable in the development of cost-effective gas cleaning process for the removal of PAHs in vehicle applications during cold start conditions.

Keywords: Dielectric barrier discharge; Oxidation; PAHs; Photocatalyst; Plasma.