Interfacial Synthesis of Conjugated Two-Dimensional N-Graphdiyne

Xiaonan Kan; Yanqi Ban; Chenyu Wu; Qingyan Pan; Hui Liu; Jianhui Song; Zicheng Zuo; Zhibo Li; Yingjie Zhao

doi:10.1021/acsami.7b17326

Interfacial Synthesis of Conjugated Two-Dimensional N-Graphdiyne

ACS Appl Mater Interfaces. 2018 Jan 10;10(1):53-58. doi: 10.1021/acsami.7b17326. Epub 2017 Dec 22.

Authors

Xiaonan Kan¹, Yanqi Ban¹, Chenyu Wu², Qingyan Pan¹, Hui Liu¹, Jianhui Song¹, Zicheng Zuo³, Zhibo Li¹, Yingjie Zhao¹

Affiliations

¹ Key Laboratory of Biobased Polymer Materials, Shandong Provincial Education Department, School of Polymer Science and Engineering, Qingdao University of Science and Technology , Qingdao 266042, China.
² Centre for Advanced Macromolecular Design, School of Chemical Engineering, The University of New South Wales , Sydney, New South Wales 2052, Australia.
³ Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, P.R. China.

PMID: 29260842
DOI: 10.1021/acsami.7b17326

Abstract

We explored the interfacial synthesis of 2D N-graphdiyne films at the gas/liquid and liquid/liquid interfaces. Triazine- or pyrazine-based monomers containing ethynyl group were polymerized through the Glaser coupling reactions at interfaces. Several layered, highly ordered and conjugated 2D N-graphdiyne were obtained. Their structures were characterized by TEM, SEM, AFM, XPS, and Raman spectra. Thin films with minimum thickness of 4 nm could be prepared.

Keywords: N-doping; diine; graphdiyne; interfacial synthesis; two-dimensional materials.