Enrichment of 57Fe isotope in neutron flux of nuclear reactors observed by Mössbauer spectroscopy

Abstract

The abundance of ⁵⁷Fe isotope in nuclear reactor core materials can be considerably enriched by neutron-capture ⁵⁶Fe(n,γ) reactions. This is demonstrated using the sections of Zr-2.5 wt.%Nb pressure tubes removed from two CANDU* reactors. The tubes contained 0.11 and 0.04wt% Fe and were irradiated for about 10 effective full power years (EFPY) up to ~10²⁶n/m² fast neutron (E > 1MeV) fluencies. The Mössbauer spectra of ⁵⁷Fe in irradiated samples indicated up to 10 times larger areas than unirradiated off-cuts from the same pressure tubes. The observed effect is in accord with the values calculated for known thermal neutron-capture cross-sections and resonance capture integrals, neutron flux profiles and spectra, and times of irradiation. The build-up of ⁵⁷Fe facilitated recording Mössbauer absorption spectra of alloys with minor amount of Fe down to ~ 400ppm, despite intense background radiation emitted by samples. These findings can open new possibilities in post-irradiation studies of alloys used in nuclear reactors and in other objects subjected to large neutron fluencies.