p-Nitrophenol degradation by Fenton's oxidation in a bubble column reactor

Abstract

This paper reports on a study of the oxidation of p-nitrophenol (PNP) in a bubble column reactor (BCR). The use of the air stream aimed to provide perfect mixing in the liquid phase, which was successfully achieved and checked experimentally; there were no concentration gradients along the column, even at the lowest air flow rate used (Q = 1 mL/min at room temperature and atmospheric pressure). The effect of the operating variables was assessed, and a total reduction of PNP was reached, as well as mineralization of 49.2%, oxidant consumption of 90.3%, and with an efficiency of use - η_H2O2 - of 0.09 mg C/mg H₂O₂, under the best operating conditions found - Q = 1 mL/min, [H₂O₂] = 1.6 g/L, [Fe²⁺] = 80 mg/L, pH = 3.0 and T = 22-24 °C - (after 120 min of reaction). Following this, various strategies were developed for improving the mineralization rate; it was found that the addition of H₂O₂ every 5 min and readjusting the pH after 30 min of reaction allow the attainment of a much higher TOC removal (75.1%) and efficiency of oxidant use (η_H2O2 = 0.17 mg C/mg H₂O₂) with less oxidant. A reaction mechanism was proposed, based on intermediates identified that include p-nitrocatechol - PNC, p-benzoquinone - PB, hydroquinone - HQ - and carboxylic acids (oxalic, maleic and fumaric). Since the performance achieved in the BCR was good, and very similar to that obtained in a conventional batch reactor, it was possible to verify the efficacy of carrying out the Fenton process in this reactor configuration, which in our future work will focus on the treatability of industrial effluents.

Keywords: Advanced oxidation process; Bubble column reactor; Fenton's oxidation; p-Nitrophenol.