Sodium and acidic alginate foams with hierarchical porosity: Preparation, characterization and efficiency as a dye adsorbent

Carbohydr Polym. 2017 Dec 15:178:78-85. doi: 10.1016/j.carbpol.2017.09.022. Epub 2017 Sep 8.

Abstract

A novel approach for the preparation of sodium alginate foams by ice-templating, followed by freeze-drying was described. Important effects of the preparation parameters on the macroporous structure of the final materials could be evidenced. A functionalization procedure for the preparation of acidified macro/meso-porous foams with high surface area was optimized and the efficiency of one alginic acid foam was demonstrated for the adsorption of a basic dye (methylene blue) from aqueous solution. The comparison of the maximum monolayer adsorption capacity of this adsorbent with the values already reported for other biosorbents clearly identified alginic acid foams as competitive sorbents for the removal of methylene blue from aqueous solutions.

Keywords: Alginic acid; Biocompatible adsorbent; Biopolymers; CT-scan; Foams; Hierarchical porosity.