Hispanane-Type Diterpenoid and Secoiridoid Glucosides from Viburnum cylindricum

Chem Biodivers. 2018 Jan;15(1). doi: 10.1002/cbdv.201700418. Epub 2018 Jan 5.

Abstract

Three hitherto unknown compounds, including one new hispanane-type diterpenoid glucoside, namely viburnumoside (1), two new secoiridoid glucosides, 7α-galloyloxysweroside (2), and 7β-galloyloxysweroside (3), together with ten known compounds (4 - 13) were isolated from the ethanol extract of twigs and leaves of Viburnum cylindricum. Their structures were elucidated on the basis of extensive spectroscopic studies, and the absolute configuration of compound 1 was confirmed by the experimental and calculated electronic circular dichroism (ECD) data.

Keywords: Viburnum cylindricum; ECD calculation; diterpenoid; secoiridoid glucoside; structure elucidation.

MeSH terms

  • Diterpenes / chemistry*
  • Diterpenes / isolation & purification
  • Glucosides / chemistry*
  • Glucosides / isolation & purification
  • Iridoid Glucosides / chemistry*
  • Iridoid Glucosides / isolation & purification
  • Molecular Structure
  • Quantum Theory
  • Viburnum / chemistry*

Substances

  • Diterpenes
  • Glucosides
  • Iridoid Glucosides
  • viburnumoside