Microstructure and physical properties of nano-biocomposite films based on cassava starch and laponite

Int J Biol Macromol. 2018 Feb;107(Pt B):1576-1583. doi: 10.1016/j.ijbiomac.2017.10.031. Epub 2017 Oct 6.

Abstract

The aim of this research was to study the effects of laponite concentrations on some properties of nano-biocomposite films based on cassava starch, focusing mainly the relation between the properties of the surface microstructure and roughness, water contact angle and gloss. Nano-biocomposite films were produced by casting. We analyzed gloss, color, opacity, water contact angle, crystallinity by X-ray diffraction, and microstructure by scanning electron microscopy and atomic force microscopy. Texture parameters (energy, entropy and fractal dimension) were extracted from micrographs. We observed a great impact of laponite in the morphology of nano-biocomposite films. Texture parameters correlated with surface heterogeneity and roughness. Finally, surface roughness affected the surface hydrophilicity of nano-biocomposite films. Laponite platelets were exfoliated and/or intercalated with amylose and amylopectin chains. This research reports new information on the effects of laponite concentrations on the morphological, optical and wetting properties of nano-biocomposite films aiming future industrial applications.

Keywords: Gloss; Image analysis; Microstructure; Nano-biocomposite films; Water contact angle.

MeSH terms

  • Biocompatible Materials / chemistry*
  • Color
  • Entropy
  • Manihot / chemistry*
  • Microscopy, Atomic Force
  • Nanoparticles / chemistry*
  • Nanoparticles / ultrastructure
  • Silicates / chemistry*
  • Starch / chemistry*
  • Water / chemistry
  • X-Ray Diffraction

Substances

  • Biocompatible Materials
  • Silicates
  • Water
  • Starch
  • laponite