Multistage optimizations of slow pyrolysis synthesis of biochar from palm oil sludge for adsorption of lead

Abstract

This research investigated the removal of lead (Pb²⁺) by a novel biochar derived from palm oil sludge (POS-char) by slow pyrolysis. Multistage optimizations with central composite design were carried out to firstly optimize pyrolysis parameters to produce the best POS-char for Pb²⁺ removal and secondly to optimize adsorption conditions for the highest removal of Pb²⁺. The optimum pyrolysis parameters were nitrogen flowrateof30mLmin^-1, heating rateof10°Cmin^-1, temperatureof500°C and timeof30min. The optimum Pb²⁺ adsorption conditions were concentrationof200mgL^-1, timeof60min, dosageof0.3g and pH of 3.02. The various functional groups within POS-char played a vital role in Pb²⁺ uptake. Regeneration was demonstrated to be feasible using hydrochloric acid. Adsorption equilibrium was best described by Freundlich model. At low concentration range, adsorption kinetic obeyed pseudo-first-order model, but at high concentration range, it followed pseudo-second-order model. Overall, the results highlighted that POS-char is an effective adsorbent for Pb²⁺ removal.

Keywords: Adsorption; Biochar; Palm oil waste; Pb(2+); Process optimization.