The effect of Nanocrystalline cellulose/Gum Arabic conjugates in crosslinked membrane for antibacterial, chlorine resistance and boron removal performance

J Hazard Mater. 2018 Feb 5:343:68-77. doi: 10.1016/j.jhazmat.2017.09.023. Epub 2017 Sep 14.

Abstract

In this work, we developed hybrid membranes integrated with Nanocrystalline cellulose (NCC)/Gum Arabic (GuA) conjugates using crosslinked Poly (vinyl alcohol) (PVA) as a matrix phase with the addition of PEO-PPO-PEO block copolymer that insured pore formation. At first, the NCC was prepared from microcrystalline cellulose via acid hydrolysis process. The performance property of hybrid NCC/GuA was measured using boron removal. The results showed that the rejection capability enhanced as compared to the control membranes, especially at 0.1wt% of NCC the selectivity is up to 92.4% with the flux rate of 21.3L/m2.h. Moreover, the GuA in NCC/GuA conjugate significantly enhances the antibacterial activity by hindering the bacterial attachment to the surface as both of them carry the negative charge. Also by providing the active sites responsible for hydrogen bonding thus enhancing the hydrophilic character resulted in increased permeation flux rate. Therefore, the NCC/GuA conjugated membranes have great potentials for boron removal.

Keywords: Boron; Gum Arabic; Nanocrystalline cellulose; PEOPPO- PEO block copolymer; Polyvinyl alcohol.

MeSH terms

  • Anti-Bacterial Agents / chemistry*
  • Boron / chemistry*
  • Cellulose / chemistry*
  • Chlorine / chemistry
  • Cross-Linking Reagents / chemistry
  • Drug Resistance, Bacterial
  • Escherichia coli / drug effects
  • Gum Arabic / chemistry*
  • Membranes, Artificial*
  • Nanoparticles / chemistry*
  • Polyethylene Glycols / chemistry
  • Polyvinyl Alcohol / chemistry
  • Propylene Glycols / chemistry
  • Silanes / chemistry
  • Water Purification / instrumentation*
  • Water Purification / methods

Substances

  • Anti-Bacterial Agents
  • Cross-Linking Reagents
  • Membranes, Artificial
  • PEO-PPO-PEO
  • Propylene Glycols
  • Silanes
  • Polyethylene Glycols
  • tetraethoxysilane
  • Chlorine
  • Gum Arabic
  • Polyvinyl Alcohol
  • Cellulose
  • Boron