Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride

Abstract

The new iron(IV) nitride complex PhB(ⁱPr₂Im)₃Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(ⁱPr₂Im)₃Fe(CN)(N₂)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne ⁱPr₂N-C≡C-NⁱPr₂. The iron complex is in equilibrium with an N₂-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C₆F₅)₃ provides the cyanoborane derivative.