We present infrared multiple photon dissociation (IRMPD) spectra of (H2O)nO˙- and (H2O)nOH- cluster ensembles for n[combining macron] ≈ 8 and 47 in the range of 2400-4000 cm-1. Both hydrated ions exhibit the same spectral features, in good agreement with theoretical calculations. Decomposition of the calculated spectra shows that bands originating from H2OO˙- and H2OOH- interactions span almost the whole spectral region of interest. Experimentally, evaporation of OH˙ is observed to a small extent, which requires interconversion of (H2O)nO˙- into (H2O)n-1OH˙OH-, with subsequent H2O evaporation preferred over OH˙ evaporation. The modeling shows that (H2O)nO˙- and (H2O)n-1OH˙OH- cannot be distinguished by IRMPD spectroscopy.