Metal-Based Diversity for Crystalline Metal-Fullerene Frameworks

Andreas Kraft; Chantal Roger; David Schmidt; Johannes Stangl; Klaus Müller-Buschbaum; Florian Beuerle

doi:10.1002/chem.201703709

Metal-Based Diversity for Crystalline Metal-Fullerene Frameworks

Chemistry. 2017 Nov 13;23(63):15864-15868. doi: 10.1002/chem.201703709. Epub 2017 Oct 10.

Authors

Andreas Kraft^{1

2}, Chantal Roger^{1

2}, David Schmidt^{1

2}, Johannes Stangl³, Klaus Müller-Buschbaum³, Florian Beuerle^{1

2}

Affiliations

¹ Universität Würzburg, Institut für Organische Chemie, Am Hubland, 97074, Würzburg, Germany.
² Center for Nanosystems Chemistry (CNC), & Bavarian Polymer Institute (BPI), Theodor-Boveri-Weg, 97074, Würzburg, Germany.
³ Universität Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074, Würzburg, Germany.

PMID: 28891199
DOI: 10.1002/chem.201703709

Abstract

Four different three-dimensional metal-fullerene frameworks were synthesized through polymerization of two C₆₀ -derived dodecaacids with varying alkyl spacers in the presence of Ca²⁺ , Cu²⁺ or Cd²⁺ ions. Structural analysis of the frameworks was performed by single-crystal X-ray diffraction and porosity of the materials was investigated by sorption measurements.

Keywords: cadmium; calcium; copper; fullerenes; metal-organic frameworks.