High-Resolution Spin-on-Patterning of Perovskite Thin Films for a Multiplexed Image Sensor Array

Adv Mater. 2017 Oct;29(40). doi: 10.1002/adma.201702902. Epub 2017 Aug 28.

Abstract

Inorganic-organic hybrid perovskite thin films have attracted significant attention as an alternative to silicon in photon-absorbing devices mainly because of their superb optoelectronic properties. However, high-definition patterning of perovskite thin films, which is important for fabrication of the image sensor array, is hardly accomplished owing to their extreme instability in general photolithographic solvents. Here, a novel patterning process for perovskite thin films is described: the high-resolution spin-on-patterning (SoP) process. This fast and facile process is compatible with a variety of spin-coated perovskite materials and perovskite deposition techniques. The SoP process is successfully applied to develop a high-performance, ultrathin, and deformable perovskite-on-silicon multiplexed image sensor array, paving the road toward next-generation image sensor arrays.

Keywords: dewetting; high-resolution patterning; perovskite patterning; perovskite photodiode.