Air gasification of biogas-derived digestate in a downdraft fixed bed gasifier

Abstract

Digestate is a byproduct from biomass anaerobic digestion process. Gasification of dried digestate to produce gasesous product might be a promising route. In this work, air gasification of digestate with high ash content was performed in a downdraft fixed bed gasifier at temperature varying from 600°C to 800°C and air equivalence ratio (ER) ranging from 0.25 to 0.30. The ash melting properties were firstly detected by the Intelligent Ash Melting Point Test, and the by-products (biochar and ash) were analyzed. The results showed that no ash slagging was observed and therefore it is feasible to operate digestate gasification under 800°C and ER ranging from 0.25 to 0.30. High temperature favored gas production, 800°C is proposed for digestate gasification in the present study. ER with a medium value improved gas quality and cold gas efficiency (CGE), and the optimal LHV of 4.78MJ/Nm³ and CGE of 67.01% were obtained with ER of 0.28. High ER favored the increase of gas yield and decrease of tar concentration, and the optimal gas yield of 2.15 Nm³/kg and tar concentration of 1.61g/Nm³ were achieved with ER of 0.30. Improved molar ratio of H₂/CO varying from 1.03 to 1.08 was obtained at 800°C, indicating gaseous product has the potential for chemical synthesis processes (1<H₂/CO<2). The byproducts biochar and ash could be applied on land as fertilizer.

Keywords: Air gasification; Digestate; Fertilizer; Fixed-bed gasifier; Gaseous product.