A highly stable polyoxometalate-based metal-organic framework with an ABW zeolite-like structure

Xiao-Xin Li; Feng-Cui Shen; Jiang Liu; Shun-Li Li; Long-Zhang Dong; Qiang Fu; Zhong-Min Su; Ya-Qian Lan

doi:10.1039/c7cc05552h

A highly stable polyoxometalate-based metal-organic framework with an ABW zeolite-like structure

Chem Commun (Camb). 2017 Sep 5;53(72):10054-10057. doi: 10.1039/c7cc05552h.

Authors

Xiao-Xin Li¹, Feng-Cui Shen, Jiang Liu, Shun-Li Li, Long-Zhang Dong, Qiang Fu, Zhong-Min Su, Ya-Qian Lan

Affiliation

¹ Institute of Functional Material Chemistry, Department of Chemistry, National & Local United Engineering Lab for Power Battery, Northeast Normal University, Changchun 130024, Jilin, P. R. China. zmsu@nenu.edu.cn.

PMID: 28840211
DOI: 10.1039/c7cc05552h

Abstract

A novel polyoxometalate-based metal-organic framework (POMOF) with an ABW network, NENU-601, was synthesized in situ. To the best of our knowledge, this is the first POMOF with a zeolite-like structure, which was designed by regulating the length and angle of mixed ligands and rationally choosing suitable Polyoxometalates (POMs) as nodes.