Two-dimensional metal chalcogenides analogous NiSe2 nanosheets and its efficient electrocatalytic performance towards glucose sensing

Sakthivel Mani; Sukanya Ramaraj; Shen-Ming Chen; Bose Dinesh; Tse-Wei Chen

doi:10.1016/j.jcis.2017.08.018

Two-dimensional metal chalcogenides analogous NiSe₂ nanosheets and its efficient electrocatalytic performance towards glucose sensing

J Colloid Interface Sci. 2017 Dec 1:507:378-385. doi: 10.1016/j.jcis.2017.08.018. Epub 2017 Aug 8.

Authors

Sakthivel Mani¹, Sukanya Ramaraj¹, Shen-Ming Chen², Bose Dinesh³, Tse-Wei Chen¹

Affiliations

¹ Electroanalysis and Bioelectrochemistry Lab, Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan.
² Electroanalysis and Bioelectrochemistry Lab, Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan. Electronic address: smchen78@ms15.hinet.net.
³ Nano and Bioelectrochemistry Research Laboratory, Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology University, Vellore 632 014, Tamil Nadu, India. Electronic address: bosedinesh210@gmail.com.

PMID: 28806657
DOI: 10.1016/j.jcis.2017.08.018

Abstract

Recently, 2D layered transition-metal dichalcogenide materials have received great consideration because of their unique electronic properties, large surface area and high electrocatalytic activity. In this connection, for the first time the similar nanostructured material of NiSe₂ nanosheets (NiSe₂-NS) has been synthesized by a facile hydrothermal method for electrocatalytic applications. Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), Energy Dispersive X-ray analysis (EDX), X-ray diffraction spectrum (XRD) results confirmed the formation of NiSe₂-NS with required stoichiometry and morphology. Electrochemical Impedance Spectroscopy (EIS) data indicate that electron transfer is facile at the NiSe₂-NS modified glassy carbon electrode (GCE). It has been as an electrode modifier for glucose sensing applications. The electrochemical studies were performed for NiSe₂-NS modified GCE using Cyclic Voltammetry (CV) and amperometric i-t techniques. The results are suggesting the effective response of NiSe₂-NS/GCE with a very low limit of detection (LOD) and sensitivity of 23nM and 5.6μAμM^-1cm^-2 respectively. Moreover, the selectivity data exhibited excellent anti-interference property of NiSe₂-NS/GCE towards glucose in the presence of possible interfering agents viz. Ascorbic acid, dopamine, glucose.

Keywords: Chalcogenide; Hydrothermal synthesis; NiSe(2); Non-enzymatic glucose sensor.