Detecting long-term temporal trends in sediment-bound metals in the western Adriatic (Mediterranean Sea)

Mar Pollut Bull. 2017 Nov 15;124(1):270-285. doi: 10.1016/j.marpolbul.2017.07.026. Epub 2017 Aug 9.

Abstract

Major and trace metal concentrations were determined in western Adriatic sediment cores. Based on sediment chronology, the earliest anthropogenic influence appeared as a Zn and Pb increase in the Po River prodelta starting from ~1914. The increasing contamination signal of these trace metals propagated southward as far as 450km with a growing delay, taking ~10years to reach the south Adriatic Sea. Although greater inventories of excess trace metals in the northern sector pointed to the influence of the intense human activities in the Po River drainage basin and Venice lagoon system, we observed a reduction of excess trace metals from mid-1980s, related to the implementation of stricter environmental regulations on chemical wastewaters. In contrast, an increase in trace metal accumulation in surficial sediment from the 2000s in front of the cities of Ancona and Bari suggested a recent local input of trace metals, probably due to harbor activities.

Keywords: Adriatic Sea; Background levels; Historical trends of contamination; Inventories of trace metals excess; Sediment records; Trace metals.

MeSH terms

  • Environmental Monitoring
  • Geologic Sediments / chemistry*
  • Mediterranean Sea
  • Metals / analysis*
  • Trace Elements / analysis*
  • Water Pollutants, Chemical / analysis*

Substances

  • Metals
  • Trace Elements
  • Water Pollutants, Chemical