Effect of Extrusion on the Mechanical and Rheological Properties of a Reinforced Poly(Lactic Acid): Reprocessing and Recycling of Biobased Materials

Materials (Basel). 2015 Oct 19;8(10):7106-7117. doi: 10.3390/ma8105360.

Abstract

The aim of this research paper is to study the behaviour of a common used biopolymer (Poly(Lactic Acid) (PLA)) after several reprocesses and how two different types of additives (a melt strength enhancer and a nanoadditive) affect its mechanical and rheological properties. Systematic extraction of extrudate samples from a twin-screw compounder was done in order to study the effect in the properties of the reprocessed material. Detailed rheological tests on a capillary rheometer as well as mechanical studies on a universal tensile machine after preparation of injected specimens were carried out. Results evidenced that PLA and reinforced PLA materials can be reprocessed and recycled without a remarkable loss in their mechanical properties. Several processing restrictions and specific phenomena were identified and are explained in the present manuscript.

Keywords: extrusion compounding; mechanical; melt strength enhancer; nanoadditive; nanocomposites; polylactic acid; reprocess; rheology; viscosity.