The few-mode fiber (FMF) based Brillouin sensing operated in quasi-single mode (QSM) has been reported to achieve the distributed curvature measurement by monitoring the bend-induced strain variation. However, its practicality is limited by the inherent temperature-strain cross-sensitivity of Brillouin sensors. Here we proposed and experimentally demonstrated an approach for simultaneously distributed curvature and temperature sensing, which exploits a hybrid QSM operated Raman-Brillouin system in FMFs. Thanks to the larger spot size of the fundamental mode in the FMF, the Brillouin frequency shift change of the FMF is used for curvature estimation while the temperature variation is alleviated through Raman signals with the enhanced signal-to-noise ratio (SNR). Within 2 minutes measuring time, a 1.5 m spatial resolution is achieved along a 2 km FMF. The worst resolution of the square of fiber curvature is 0.333 cm-2 while the temperature resolution is 1.301 °C at the end of fiber.