Phosphomolybdic acid-responsive Pickering emulsions stabilized by ionic liquid functionalized Janus nanosheets

Qing Bo Meng; Peng Yang; Tianyang Feng; Xuyang Ji; Qian Zhang; Daliang Liu; Shuyao Wu; Fuxin Liang; Zhaoliang Zheng; Xi-Ming Song

doi:10.1016/j.jcis.2017.07.097

Phosphomolybdic acid-responsive Pickering emulsions stabilized by ionic liquid functionalized Janus nanosheets

J Colloid Interface Sci. 2017 Dec 1:507:74-82. doi: 10.1016/j.jcis.2017.07.097. Epub 2017 Jul 27.

Authors

Affiliations

¹ Liaoning Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, China.
² Liaoning Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, China; State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
³ State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. Electronic address: liangfuxin@iccas.ac.cn.
⁴ Stephenson Institute for Renewable Energy, Department of Chemistry, University of Liverpool, Liverpool, Crown Street, Liverpool L69 7ZD, United Kingdom.
⁵ Liaoning Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials, College of Chemistry, Liaoning University, Shenyang 110036, China. Electronic address: songlab@lnu.edu.cn.

PMID: 28780337
DOI: 10.1016/j.jcis.2017.07.097

Abstract

A type of ionic liquid functionalized high-aspect-ratio Janus SiO₂ nanosheets (IL-Janus nanosheets), which possesses a side terminated by imidazolin salt groups and the opposite side terminated by phenyl groups, was prepared and its emulsification performance was investigated. The surface wettability of ionic liquid functionalized side could be tailored via simple anion exchanging, giving the amphiphilic or totally hydrophobic Janus nanosheets. The influence of several parameters including surface wettability, particle concentration, oil composition, oil-water ratio as well as initial location of the nanosheets on the stability, morphology and type of the Pickering emulsions (O/W or W/O) stabilized by the amphiphilic IL-Janus nanosheets was evaluated. The research results revealed that average emulsion droplets size was decreased with increase of nanosheets concentration below a concentration value but had almost no change beyond the concentration; catastrophic phase inversion phenomenon occurred by varying volume fraction of water phase in the oil-water systems, and transitional phase inversion could be achieved by in-situ exchanging Cl^- anion of the IL-Janus nanosheets with phosphomolybdate H₂PMo₁₂O₄₀^-. The responsiveness of Pickering emulsions towards phosphomolybdic acid is resulted from irreversible anion exchanging of Cl^- by H₂PMo₁₂O₄₀^- and the variation of surface wettability of the nanosheets.

Keywords: Ionic liquid; Janus nanosheet; Phase inversion; Phosphomolybdic acid; Pickering emulsion.