Effect of Alternating Current on the Cathodic Protection and Interface Structure of X80 Steel

Materials (Basel). 2017 Jul 25;10(8):851. doi: 10.3390/ma10080851.

Abstract

This study employs potential-monitoring techniques, cyclic voltammetry tests, alternating current (AC) voltammetry methods, and surface characterization to investigate the AC corrosion of cathodically protected X80 pipeline steel. In a non-passive neutral solution at pH 7.2, a sufficiently negative potential completely protects steel at an AC current density of 100 A/m². In an alkaline solution at pH 9.6, more serious AC corrosion occurs at more negative cathodic protection (CP) potential, whereas without CP the steel suffers negligible corrosion. In addition, the interface capacitance increases with AC amplitude. Based on these results, the AC corrosion mechanisms that function under various conditions are analyzed and described.

Keywords: AC corrosion; alkaline; capacitance; cathodic protection; neutral; passivation.