Different characterization techniques were used to study the hydrolysis and condensation reaction kinetics of 3-methacryloxypropyltrimethoxysilane (MAPTMS) to obtain open cage silsesquioxane oligomers. The formation of hydrogen bonds, which condition the chemical structures of the resulting products, was identified. Improved thermal and fire resistant behavior of unsaturated polyester (UP) composites prepared with aluminium trihydroxide (ATH) and the synthesized oligomer were registered. Opened silsesquioxane structures also showed an improvement in the mechanical properties of the char formed after firing.
Keywords: 3-methacryloxypropyltrimethoxysilane (MAPTMS); fire retardance; hydrogen bond; open silsesquioxane; thermal degradation.