Methodology for Fast and Facile Characterisation of Carbon-Based Electrodes Focused on Bioelectrochemical Systems Development and Scale Up

Materials (Basel). 2017 Jan 20;10(1):79. doi: 10.3390/ma10010079.

Abstract

The development and practical implementation of bioelectrochemical systems (BES) requires an in-depth characterisation of their components. The electrodes, which are critical elements, are usually built from carbon-based materials due to their high specific surface area, biocompatibility and chemical stability. In this study, a simple methodology to electrochemically characterise carbon-based electrodes has been developed, derived from conventional electrochemical analyses. Combined with classical electrochemical theory and the more innovative fractal geometry approach, our method is aimed at comparing and characterising the performance of carbon electrodes through the determination of the electroactive surface and its fractal dimension. Overall, this methodology provides a quick and easy method for the screening of suitable electrode materials to be implemented in BES.

Keywords: bioelectrochemical systems; carbon-based electrodes; electroactive area; fractal dimension; scale up.