Size- and Density-Controllable Fabrication of the Platinum Nanoparticle/ITO Electrode by Pulse Potential Electrodeposition for Ammonia Oxidation

Siyuan Li; Haiyan Chen; Jie Liu; Yida Deng; Xiaopeng Han; Wenbin Hu; Cheng Zhong

doi:10.1021/acsami.7b08604

Size- and Density-Controllable Fabrication of the Platinum Nanoparticle/ITO Electrode by Pulse Potential Electrodeposition for Ammonia Oxidation

ACS Appl Mater Interfaces. 2017 Aug 23;9(33):27765-27772. doi: 10.1021/acsami.7b08604. Epub 2017 Aug 11.

Authors

Siyuan Li¹, Haiyan Chen², Jie Liu¹, Yida Deng³, Xiaopeng Han³, Wenbin Hu^{1

3}, Cheng Zhong^{1

3}

Affiliations

¹ Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), School of Materials Science and Engineering, Tianjin University , Tianjin 300072, China.
² Department of Echocardiography, Zhongshan Hospital, Fudan University: Shanghai Institute of Medical Imaging, Shanghai Institute of Cardiovascular Diseases , Shanghai 200032, China.
³ Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University , Tianjin 300072, China.

PMID: 28766929
DOI: 10.1021/acsami.7b08604

Abstract

Pulse potential electrodeposition was successfully utilized to electrochemically fabricate platinum (Pt) nanoparticles on indium tin oxide (ITO) conductive glass substrates for catalysis toward ammonia electro-oxidation. The effect of deposition parameters (lower potential E_l, lower potential duration t_l, and upper potential duration t_u) on the size and number density of Pt nanoparticles was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrocatalytic activity of the Pt nanoparticle/ITO electrode for ammonia oxidation was characterized by the cyclic voltammetry (CV) method. The results showed that lower E_l and longer t_l accelerate the formation of Pt nuclei while longer t_u favors the growth of grain size to some extent, as E_l mainly tunes electrochemical overpotential while t_l and t_u affect the activation and mass transfer process. By the tuning of the deposition parameters, Pt nanoparticle/ITO electrodes with a polycrystalline nature and 5 nm-scale primary particles, could be easily modified in Pt particle size and number density. Furthermore, the Pt nanoparticle/ITO electrode shows high mass specific catalytic activity (MA) toward ammonia oxidation (1.65 mC μg^-1), much higher than that of the commercial Pt/C electrode (0.32 mC μg^-1). Additionally, the high catalytic performance results not only from the nanosize effect of Pt nanoparticles, but also from the special morphology formed during the electrodeposition process.

Keywords: ammonia oxidation; electrocatalysis; indium tin oxide; platinum nanoparticles; pulse potential electrodeposition.