Pulsed UV laser-induced modifications in optical and structural characteristics of alpha-irradiated PM-355 SSNTD

Appl Radiat Isot. 2017 Oct:128:287-291. doi: 10.1016/j.apradiso.2017.07.014. Epub 2017 Jul 8.

Abstract

Pre- and postalpha-exposed PM-355 detectors were irradiated using UV laser with different number of pulses (100, 150, 200, 300, and 400). UV laser beam energy of 20mJ per pulse with a pulse width of 9ns was incident on an area of 19.6mm2 of the samples. XRD spectra indicated that for both reference and UV-irradiated samples, the structure is amorphous, but the crystallite size increases upon UV irradiation. The same results were obtained from SEM analysis. Optical properties of PM-355 polymeric solid-state nuclear track detectors were also investigated. Absorbance measurements for all PM-355 samples in the range of 200-400nm showed that the absorption edge had a blue shift up to a certain value, and then, it had an oscillating behavior. Photoluminescence spectra of PM-355 at 250nm revealed a decrease in the broadband peak intensity as a function of the number of UV pulses, while the wavelengths corresponding to the peaks had random shifts.

Keywords: Absorbance; Alpha irradiation; PM-355 polymer; Photoluminescence; Solid-state nuclear track detector.